The nitrogen interaction with Rh(100) was studied by combining high-energy resolution core level photoelectron spectroscopy and density functional calculations. Nitrogen-induced Rh3d(5/2) surface core level shifts depend on the N-Rh local geometrical configuration. The core level shifts are dominated by initial state effects and correlate strongly with the variation of the energy position of the surface atom-projected d-band center.
Geometric and electronic structure of the N/Rh(100) system by core-level photoelectron spectroscopy: Experiment and Theory / Bianchettin, L.; Baraldi, A.; de Gironcoli, Stefano Maria; Lizzit, S.; Petaccia, L.; Vesselli, E.; Comelli, G.; Rosei, R.. - In: PHYSICAL REVIEW. B, CONDENSED MATTER AND MATERIALS PHYSICS. - ISSN 1098-0121. - 74:4(2006), pp. 1-9. [10.1103/PhysRevB.74.045430]
Geometric and electronic structure of the N/Rh(100) system by core-level photoelectron spectroscopy: Experiment and Theory
de Gironcoli, Stefano Maria;
2006-01-01
Abstract
The nitrogen interaction with Rh(100) was studied by combining high-energy resolution core level photoelectron spectroscopy and density functional calculations. Nitrogen-induced Rh3d(5/2) surface core level shifts depend on the N-Rh local geometrical configuration. The core level shifts are dominated by initial state effects and correlate strongly with the variation of the energy position of the surface atom-projected d-band center.| File | Dimensione | Formato | |
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