A glass surface may still flow below the bulk glass transition temperature, where the underlying bulk is frozen. Assuming the existence at T = T-0 of a bulk thermodynamical glass transition, we show that the glass-vapor interface is generally wetted by a liquid layer of thickness l similar to -1n(T-0 - T) when T --> T-0(-). Contrary to standard surface melting of crystals however, the integrated value of the diffusivity across the interface remains finite for T --> T-0(-). Difference in shape induced by bulk and by surface flow is discussed as a possible means of experimental detection of surface defreezing.
Surface defreezing of glasses / Jagla, E. A.; Tosatti, Erio. - In: EUROPHYSICS LETTERS. - ISSN 0295-5075. - 51:6(2000), pp. 648-654. [10.1209/epl/i2000-00387-4]
Surface defreezing of glasses
Tosatti, Erio
2000-01-01
Abstract
A glass surface may still flow below the bulk glass transition temperature, where the underlying bulk is frozen. Assuming the existence at T = T-0 of a bulk thermodynamical glass transition, we show that the glass-vapor interface is generally wetted by a liquid layer of thickness l similar to -1n(T-0 - T) when T --> T-0(-). Contrary to standard surface melting of crystals however, the integrated value of the diffusivity across the interface remains finite for T --> T-0(-). Difference in shape induced by bulk and by surface flow is discussed as a possible means of experimental detection of surface defreezing.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
