The solution structure of the two intimate ion pairs present in solution for [PtMe(eta(2)-olefin) (alpha-diimine)] BF4 compounds, their relative abundance and the consequent thermodynamic equilibrium parameters have been determined by a quantitative detection of H...F interionic dipolar interactions in the F-19, H-1-HOESY NMR spectra.

Direct observation of an equilibrium between two anion-cation orientations in olefin Pt(II) complex ion pairs by HOESY NMR spectroscopy / Macchioni, A; Magistrato, Alessandra; Orabona, I; Ruffo, F; Rothlisberger, U; Zuccaccia, C.. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - 27:3(2003), pp. 455-458. [10.1039/b212088g]

Direct observation of an equilibrium between two anion-cation orientations in olefin Pt(II) complex ion pairs by HOESY NMR spectroscopy

MAGISTRATO, ALESSANDRA;
2003

Abstract

The solution structure of the two intimate ion pairs present in solution for [PtMe(eta(2)-olefin) (alpha-diimine)] BF4 compounds, their relative abundance and the consequent thermodynamic equilibrium parameters have been determined by a quantitative detection of H...F interionic dipolar interactions in the F-19, H-1-HOESY NMR spectra.
27
3
455
458
Macchioni, A; Magistrato, Alessandra; Orabona, I; Ruffo, F; Rothlisberger, U; Zuccaccia, C.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11767/32181
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