The solution structure of the two intimate ion pairs present in solution for [PtMe(eta(2)-olefin) (alpha-diimine)] BF4 compounds, their relative abundance and the consequent thermodynamic equilibrium parameters have been determined by a quantitative detection of H...F interionic dipolar interactions in the F-19, H-1-HOESY NMR spectra.
Direct observation of an equilibrium between two anion-cation orientations in olefin Pt(II) complex ion pairs by HOESY NMR spectroscopy / Macchioni, A; Magistrato, Alessandra; Orabona, I; Ruffo, F; Rothlisberger, U; Zuccaccia, C.. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - 27:3(2003), pp. 455-458.
Titolo: | Direct observation of an equilibrium between two anion-cation orientations in olefin Pt(II) complex ion pairs by HOESY NMR spectroscopy |
Autori: | Macchioni, A; Magistrato, Alessandra; Orabona, I; Ruffo, F; Rothlisberger, U; Zuccaccia, C. |
Rivista: | |
Data di pubblicazione: | 2003 |
Volume: | 27 |
Fascicolo: | 3 |
Pagina iniziale: | 455 |
Pagina finale: | 458 |
Digital Object Identifier (DOI): | http://dx.doi.org/10.1039/b212088g |
Appare nelle tipologie: | 1.1 Journal article |