The solution structure of the two intimate ion pairs present in solution for [PtMe(eta(2)-olefin) (alpha-diimine)] BF4 compounds, their relative abundance and the consequent thermodynamic equilibrium parameters have been determined by a quantitative detection of H...F interionic dipolar interactions in the F-19, H-1-HOESY NMR spectra.
Direct observation of an equilibrium between two anion-cation orientations in olefin Pt(II) complex ion pairs by HOESY NMR spectroscopy / Macchioni, A; Magistrato, Alessandra; Orabona, I; Ruffo, F; Rothlisberger, U; Zuccaccia, C.. - In: NEW JOURNAL OF CHEMISTRY. - ISSN 1144-0546. - 27:3(2003), pp. 455-458. [10.1039/b212088g]
Direct observation of an equilibrium between two anion-cation orientations in olefin Pt(II) complex ion pairs by HOESY NMR spectroscopy
MAGISTRATO, ALESSANDRA;
2003
Abstract
The solution structure of the two intimate ion pairs present in solution for [PtMe(eta(2)-olefin) (alpha-diimine)] BF4 compounds, their relative abundance and the consequent thermodynamic equilibrium parameters have been determined by a quantitative detection of H...F interionic dipolar interactions in the F-19, H-1-HOESY NMR spectra.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
