We study the static and dynamical properties of a harmonically confined Rouse polymer coupled to a fluctuating correlated medium, which affect each other reciprocally during their stochastic evolution. The medium is modeled by a scalar Gaussian field which can feature modes with slow relaxation and long-range spatial correlations. We show that these modes affect the long-time behavior of the average position of the center of mass of the polymer, which, after a displacement, turns out to relax algebraically towards its equilibrium value. This is a manifestation of the non-Markovian nature of the effective evolution of the position of the center of mass, once the degrees of freedom of the medium have been integrated out. In contrast, we show that the coupling to the medium speeds up the relaxation of higher Rouse modes. We further characterize the typical size of the polymer as a function of its polymerization degree and of the correlation length of the medium, particularly when the system is driven out of equilibrium via the application of a constant external driving force. Finally, we study the response of a linear polymer to a tensile force acting on its terminal monomers.

Structure and dynamics of a Rouse polymer in a fluctuating correlated medium / Muzzeddu, Pietro Luigi; Venturelli, Davide; Gambassi, Andrea. - In: NEW JOURNAL OF PHYSICS. - ISSN 1367-2630. - 27:10(2025), pp. 1-24. [10.1088/1367-2630/ae09d3]

Structure and dynamics of a Rouse polymer in a fluctuating correlated medium

Muzzeddu, Pietro Luigi;Venturelli, Davide;Gambassi, Andrea
2025-01-01

Abstract

We study the static and dynamical properties of a harmonically confined Rouse polymer coupled to a fluctuating correlated medium, which affect each other reciprocally during their stochastic evolution. The medium is modeled by a scalar Gaussian field which can feature modes with slow relaxation and long-range spatial correlations. We show that these modes affect the long-time behavior of the average position of the center of mass of the polymer, which, after a displacement, turns out to relax algebraically towards its equilibrium value. This is a manifestation of the non-Markovian nature of the effective evolution of the position of the center of mass, once the degrees of freedom of the medium have been integrated out. In contrast, we show that the coupling to the medium speeds up the relaxation of higher Rouse modes. We further characterize the typical size of the polymer as a function of its polymerization degree and of the correlation length of the medium, particularly when the system is driven out of equilibrium via the application of a constant external driving force. Finally, we study the response of a linear polymer to a tensile force acting on its terminal monomers.
2025
27
10
1
24
105003
10.1088/1367-2630/ae09d3
https://arxiv.org/abs/2503.03572
Muzzeddu, Pietro Luigi; Venturelli, Davide; Gambassi, Andrea
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.11767/151112
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